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01-08-2019· At a milling speed of 500 rpm, and BPR 12, the leaching concentrations of Pb, Cu and Zn decreased with increasing milling time as shown in Fig 2The leaching concentrations of Pb, Cu and Zn in untreated soil were 1392 mgL −1, 271 mgL −1, and 11431 mgL −1, which were 273 times, 26 times, and 113 times higher than the Class III level of the Chinese Surface Water Environmental .

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In addition, the BCR sequential extraction procedure revealed that speciation shiftsof heavy metals are the root cause for the reduction of leaching concentrations; after ball milling of 4 h, the primary components of Pb, Cu and Zn in the soil were relatively stable (F2 + F3) and residual fraction (F4), which accounted for 7675%, 6706% and 4805% of total Pb, Cu and Zn, respectively

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